Nitric Acid

Nitric acid (HNO3), also known as aqua fortis (Latin for "strong water") and spirit of niter, is a highly corrosive mineral acid. The pure compound is colorless. Most commercially available nitric acid has a concentration of 68% in water.

Synonyms
Aqua fortis, Azotic acid, Hydrogen nitrate, Nitral, Nitryl hydroxide
Chemical Formula
HNO3
CAS Number
7697-37-2

Characteristics

Molar Weight
63,01 g/mol
Melting Point
- 42° C
Boiling Point
83° C
Forms
Liquid

Uses and Applications

Key applications

  • Metallurgy
  • Oxidising agent
  • Etching & Engraving
  • Metal finishing
  • Fertiliser
  • Electroplating

Industries

General Information

Nitric acid is the best known and most stable oxygen acid of nitrogen. It has the structural formula HNO3 and is also called hydrogen nitrate or “separating water”. Nitric acid is used, among other things, in the production of fertilisers as well as dyes and explosives. It is one of the most important basic materials in the chemical industry. In nature, nitric acid occurs in the form of its salts (nitrates), which play an important role in the nutrient balance.

Properties of nitric acid

Nitric acid is an inorganic mineral acid. Liquid and with a pungent odour, nitric acid can be mixed with water in any ratio. It reacts violently with ethanol and is colourless in its pure state. The chemical is one of the strongest acids and can even dissolve precious metals such as silver. Especially when exposed to light, concentrated nitric acid decomposes easily and often has a yellowish or reddish hue due to the nitrogen dioxide (NO2) dissolved in it. A solution of nitric acid and nitrogen dioxide is called "fuming nitric acid":
When it comes into contact with air or exceeds its boiling point, nitric acid decomposes, producing the reddish-brown, highly toxic nitrogen dioxide (NO2). This nitrogen dioxide gas resembles orange-brown smoke and gives "fuming nitric acid" its name. As described above, nitrogen dioxide is formed when nitric acid decomposes or reacts. It has a strong oxidising effect and thus promotes fire - so it can ignite some easily combustible materials such as wood or straw.
The synonym "separating water" for nitric acid stems from the fact that silver can be dissolved out of gold with a 50 percent solution of the chemical, i.e. the metals gold and silver can be separated from each other. Concentrated nitric acid reacts with other acids. One of the best-known compounds is that with hydrochloric acid (HCl), producing the so-called "aqua regis" (Latin), also known as royal acid, which can even dissolve precious metals such as gold and platinum. The salts of nitric acid are formed from the reaction of nitric acid with metals.
The salts (and esters) of nitric acid are called nitrates. The acid owes its name to them, derived from the common names of some of its alkali and alkaline earth salts, which end with the name saltpetre - for example sodium nitrate (Chile saltpetre), potassium nitrate (potassium saltpetre), ammonium nitrate (ammonium saltpetre), calcium nitrate (calcium saltpetre or mason's saltpetre) or barium nitrate (barytes saltpetre). Since 1908, nitric acid has been produced on an industrial scale by catalytic oxidation of ammonia using the so-called Ostwald process.
Nitric acid is used in different concentrations. A 65- to 69-percent solution is considered concentrated nitric acid, which is mostly used in laboratories. Industry usually uses nitric acid in a concentration of 68 percent. A 100 per cent solution of the chemical is rarely used. Nitric acid may be freely traded in a concentration of up to three percent.
Chemist testing in the laboratory, Duisburg, Germany

Nitric acid in the chemical industry

Nitric acid is an important component of the chemical industry. It is used for the production of chemical compounds, especially those containing nitrates, such as phosphoric acid, oxalic acid, collodion and amines. These compounds are used, for example, in the production of fertilisers.

Nitric acid in the jewellery industry

Jewellers use nitric acid to determine the gold content; it is referred to here as testing acid. In addition, nitric acid is used as separating water to separate gold and silver, and in mixtures with hydrochloric acid ("aqua regia") to dissolve gold and for gilding.
Internal rotor of a steam Turbine at workshop

Nitric acid in the metal industry

In the metal industry, nitric acid is used for pickling, burnishing and polishing metals.

Nitric acid in the explosives industry

Nitric acid is used in the manufacture of nitroglycerin and other nitrate-based explosives. Potassium nitrate, a salt of nitric acid, is a component of gunpowder.
Cropped shot of a woman cleaning a kitchen counter at home

Nitric acid in the cleaning industry

Nitric acid is used in cleaning agents because it makes greases water-soluble and - because it is corrosive - can also dissolve lime or rust stains.
However, agents containing nitric acid should only be used in industry, for example when cleaning tanks, pipes or equipment in the food processing industry. In consumer products, nitric acid is de facto no longer used, as it can cause health damage in high concentrations and if used improperly.

Other uses of nitric acid

The chemical is used in the production of celluloid, nitro and zapon varnishes, and in rocket propellants as an oxidising agent. Nitric acid is also suitable for nitration of organic substances in the production of dyes, medicines and disinfectants. Silver nitrate produced from nitric acid is used in the photographic industry.